The high melting point of PA1010 results in a high heat deflection temperature that can be advantageous for some applications. In addition, other factors such as the adoption of alternative production processes for sebacic acid is expected to trigger the sebacic acid market toward witnessing a CAGR of over 5% during the forecast period. This category of injectable material includes low molecular weight monomers that are synthesized by reacting diacids, such as sebacic acid (SA), 1,3–bis(carboxyphenoxy) propane (CPP) and 1,6–bis(carboxyphenoxy) hexane (MCPH) with methacrylic anhydride (Burkoth and Anseth, 2000; Burkoth et al., 2000) (Fig. The castor oil is treated with caustic soda at high temperature, for example 250 °C, so that saponification, leading to the formation of ricinoleic acid, is followed by a reaction giving sebacic acid and octan-2-ol: Because of the by-products formed, the yield of sebacic acid is necessarily low, and in practice, yields of 50–55% (based on the castor oil) are considered to be good. REACH registered substance data was upgraded on 9th November. Use descriptors are adapted from ECHA guidance to improve readability and may not correspond textually to descriptor codes described in Chapter R.12: Use Descriptor system of ECHA Guidance on information requirements and chemical safety assessment. Brydson, in Plastics Materials (Seventh Edition), 1999. Other names: Sebacic acid; Decanedicarboxylic acid; 1,10-Decanedioic acid; 1,8-Octanedicarboxylic acid; Seracic acid; USAF HC-1; n-Decanedioic acid; NSC 19492; Ipomic acid This substance is used for the manufacture of: chemicals. Sebacic acid is also a raw material to produce sebacate diesters (DOS, DBS, …), used in complexed greases or lubricants. InfoCards are generated automatically based on the data available at the time of generation. This substance is used in the following products: laboratory chemicals, water treatment chemicals, pH regulators and water treatment products, water softeners, polymers and coating products. Since these monomers have comparatively low molecular weight (Mn = ~500–1000) and crosslinking occurs only at the chain ends, their crosslinked network has higher crosslinking density and thus higher mechanical properties than most injectable materials. In that case, the ATP (Adaptation to Technical Progress) number is displayed. Examples include recommended measures on fire-fighting, transport and recycling and disposal. Figure 8.24. Release to the environment of this substance can occur from industrial use: of substances in closed systems with minimal release. the electronic edition of the Official Journal of the European Union. 61–69). According to the notifications provided by companies to ECHA in REACH registrations no hazards have been classified. This website uses cookies to ensure you get the best experience on our websites. If the substance is covered by more than one CLH entry (e.g. EC Number 203-845-5. Please note: Precautionary measures and guidance on safe use concern the use and handling of the specific substance as such, not of the presence of the substance in other articles or mixtures. If generated, ... Sebacic acid (8Cl) Registration dossier . 4.3), a C-20 chain fatty acid, has also been evaluated to promote the acquisition of the brown adipocyte morphology, thereby facilitating a coordinate induction of the mRNAs for GLUT4 gene markers of brown adipocyte differentiation (Schluter et al., 2002, pp. Figure 4.3. By extrapolation, 1 mm thick disks of PCPP will completely degrade in more than three years. Please see the following for information about the library and its accompanying search program. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. The molecular structure is based on structures generated from information available in ECHA’s databases. Manufacturers and trade names: Evonik Degussa AG VESTAMID® Terra; DuPont™ Zytel® RS (Table 8.39). Get medical attention. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Details of dossier compliance checks and testing proposal evaluation. It does not represent a new labelling, classification or hazard statement, neither reflect other factors that affect the susceptibility of the effects described, such as duration of exposure or substance concentration (e.g. gloves, shoes, purses, furniture). Precautionary statements - describe recommended measures to minimise or prevent adverse effects resulting from exposure to a hazardous product or improper storage or handling of a hazardous product. binding agent in paints and coatings or adhesives). Additionally, if available, information on the use of the substance and how consumers and workers are likely to be exposed to it can also be displayed here. Date: 10 July 2019: Source: Own work: Author: User:Edgar181: Permission (Reusing this file) Public domain Public domain false false: I, the copyright holder of this work, release this work into the public domain. For example, poly(ethylene terephthalate-co-butylene terephthalate-co-ethylene adipate-co-butylene adipate) (PET-co-PBT-co-PEA-co-PBA) copolyesters, due to their resemblance to the homologous PBT-co-PBA in terms of physical and mechanical properties were suggested for similar applications as the latter copolymer, namely as films for agriculture and household products, or as a hydrophobic-protecting coating for food containers [60,113]. See Table 8.3 for typical properties of nylon 6.10 polymer. It is a white flake or powdered solid. Get medical attention This enables these materials to maintain > 70% of their tensile modulus and their architectural integrity at 50% mass loss (Muggli et al., 1999). Public (risk management) activities co-ordination table. If a substance is classified under multiple CLH entries, a link to the C&L Inventory is provided to allow users to view CLH information associated with the substance and no text is automatically generated for the InfoCard. All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. BPR regulation aims to improve the functioning of the biocidal products market in the EU, while ensuring a high level of protection for humans and the environment. The report analyzes, tracks, and presents the worldwide market size of the leading players in each region around … Despite its crystallinity, PA1010 can be used to manufacture films with good transparency compared to other semicrystalline polyamides. Linear Formula HO 2 C(CH 2) 8 CO 2 H . MarketandResearch.biz have recently added a new research review in its database titled, Global Sebacic Acid Market 2019 by Manufacturers, Regions, Type and Application, Forecast to 2024 which offers an acknowledged and extensive analysis of the immediate state of the market. The substance identifiers displayed in the InfoCard are the best available substance name, EC number, CAS number and/or the molecular and structural formulas. It produces high purity sebacic acid from readily available adipic acid. Molecular Weight 202.25 . Laurence W. McKeen, in Film Properties of Plastics and Elastomers (Third Edition), 2012. This information has not been reviewed or verified by ECHA, and may change without prior notice. This substance can be found in products with material based on: plastic (e.g. In its pure state it is a white flake or powdered crystal. More hydrophobic polymers, PCPP and PCPP-SA 85:15, displayed constant erosion kinetics over eight months. Sebaceus is Latin for tallow candle, sebum is Latin for tallow, and refers to its … (a) Flexible packaging film; (b) coated paper cup; and (c) packaging film [114]. The Prior Informed Consent Regulation administers the import and export of certain hazardous chemicals and places obligations on companies who wish to export these chemicals to non-EU countries. Degradation profiles of compression molded poly[bis(p-carboxyphenoxy)propane anhydride] and its copolymer with sebacic acid in 0.1 M pH phosphate buffer at 37°C. 4.13). the products in which the substance may be used) may refer to uses as intermediate and under controlled conditions, for which there is no consumer exposure. The process consists of three steps. Sebacic acid (13) (Fig. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. REACH registration dossiers have greater data requirements (such as supporting studies) than do notifications under CLP. If generated, an InChI string will also be generated and made available for searching. REACH regulation aims to improve the protection of human health and the environment from the risks that can be posed by chemicals. Sebacic dihydrazide. The CLP Regulation makes sure that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union. Beilstein/REAXYS Number 1210591 . ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. URL: https://www.sciencedirect.com/science/article/pii/B9780323358248000189, URL: https://www.sciencedirect.com/science/article/pii/B9780750641326500590, URL: https://www.sciencedirect.com/science/article/pii/S0065237708602124, URL: https://www.sciencedirect.com/science/article/pii/B9781845693879500084, URL: https://www.sciencedirect.com/science/article/pii/B9780444533494002272, URL: https://www.sciencedirect.com/science/article/pii/B9781845695880500048, URL: https://www.sciencedirect.com/science/article/pii/B9781455725519000086, URL: https://www.sciencedirect.com/science/article/pii/B9780815513575500048, URL: https://www.sciencedirect.com/science/article/pii/B9780128094501000041, URL: https://www.sciencedirect.com/science/article/pii/B9780323313063000075, Brydson's Plastics Materials (Eighth Edition), Polymer Systems for Controlled Release of Macromolecules, Immobilized Enzyme Medical Bioreactors, and Tissue Engineering, More hydrophobic polymers, PCPP and PCPP-SA 85:15, displayed constant erosion kinetics over eight months. Sebacic acid dihydrazide. Some substance identifiers may have been claimed confidential, or may not have been provided, and therefore not be displayed. The InfoCard summarises the non-confidential data of a substance held in the databases of the European Chemicals Agency (ECHA). 58 / Monday, March 26, 2012 / Rules and Regulations 10/12/2015 EN (English US) 3/5 Interaction of these two materials at higher temperatures leads to the formation of sebacic acid, as the sodium salt, and capryl alcohol. Chemsrc provides Sebacic acid(CAS#:111-20-6) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. These notifications can be provided by manufacturers, importers and downstream users. The molecular structure is based on structures generated from information available in ECHA’s databases. Get medical attention Sebacic and succinic acid derived plasticised PVC for the inhibition of biofouling in its initial stages. This section provides links to the list of precautions (precautionary statements) and to the guidance on safe use, if they have been provided in REACH registration dossiers. This section is based on three sources for information (harmonised classification and labelling (CLH), REACH registrations and CLP notifications). The Support section provides tools and practical guidance to companies which have responsibilities under the EU chemicals legislation. MOL SDF 3D-SDF PDB SMILES InChI. Chemical structure of fatty acids (13–15). Other relevant information includes the following: To see the full list of notified classifications and to get more information on impurities and additives relevant to classification please consult the C&L Inventory. 1,10-Decanedioic acid; Sebacic acid; Octadecanedioic acid Docosanedioic acid azelaic acid, dipotassium salt tin(ii)dodecanoate ZINC PALMITATE 15-Bromopentadecanoic acid 12 ... ChemWindow structure drawing, spectral analysis, and more. The polymer has a melting point of around 216 °C and a low water absorption of around 1–1.2% at 21 °C and 65% RH, which gives it better dimensional stability and electrical properties than nylon 6 and nylon 6.6.It is a commercially important polymer and is often used in place of nylon 6 and nylon 6.6 in engineering plastics applications. Electrolysis of the potassium salt of monomethyl adipate in a mixture of methanol and water gives dimethyl sebacate. Moreover, these copolyesters can be advantageously prepared from glycolyzed postconsumed PET obtained by chemical recycling of PET. Sebacic acid and hexamethylene diisocyanate react through condensation polymerization to produce Nylon 6-10. The ‘Hazard classification’ and labelling section uses the signal word, pictogram(s) and hazard statements of the substance under the harmonised classification and labelling (CLH) as its primary source of information. Stars This entity has been manually annotated by … Sebacic acid is a naturally occurring dicarboxylic acid with the structure (HOOC)(CH2)8(COOH). Synonym: Decanedioic acid 1,10-dimethyl ester, Dimethyl decanedioate, NSC 9415, Sebacic acid dimethyl ester Linear Formula: CH 3 OCO(CH 2 ) 8 COOCH 3 Molecular Weight: 230.30 More information about CAS and the CAS registry can be found here. This is unique source of information on the chemicals manufactured and imported in Europe. The CLP Regulation ensures that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union through classification and labelling of chemicals. Sebacic acid is a naturally occurring dicarboxylic acid with the formula (CH2)8(CO2H)2. Close Find out more on how we use cookies. The Waste Framework Directive aims to protect the environment and human health from the generation and management of waste and to improve efficient use of resources. Sebacic Acid. Three examples of applications of the aliphatic-aromatic copolyester ecoflex® and ecovio of BASF SE. Sebacic acid is a naturally occurring dicarboxylic acid with the structure (CH₂)₈. Oligomerization can occur during the synthesis of the methacrylated monomer, and oligomerization occurs to a greater extent during the methacrylated CPP synthesis. Articles of Sebacic acid are included as well. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. It is noted that there are different magnifications according to pH of 4, 7, and 12 (see, different scales of 20, 2, and 0.2 μm, respectively). Additional Academic Resources. If available, additional information on classification and labelling (C&L) is derived from REACH registration dossiers submitted by industry. Bloomberg the Company & Its Products The Company & its Products Bloomberg Terminal Demo Request Bloomberg Anywhere Remote Login Bloomberg Anywhere Login Bloomberg Customer Support Customer Support 8.24. Substances may have impurities and additives that lead to different classifications. Sebacic acid is a derivative of castor oil. Sebacic acid is an alpha,omega-dicarboxylic acid that is the 1,8-dicarboxy derivative of octane. MDL number MFCD00004440. The sebacic acid market is driven by demand for sebacic acid from the automotive industry. Release to the environment of this substance can occur from industrial use: in processing aids at industrial sites, in the production of articles, formulation of mixtures, as an intermediate step in further manufacturing of another substance (use of intermediates), as processing aid and for thermoplastic manufacture. The CLP Regulation uses the UN Global Harmonised System (GHS) and European Union Specific Hazard Statements (EUH). The type of uses and classifications may vary between different submissions to ECHA and for a full understanding it is recommended to consult the source data. Film ; ( b ) coated paper cup ; and ( C & L ) is derived from registration... In moduli for these two materials at higher temperatures leads to the provided... Improve the protection of human health or the environment of this salt is coolant ( anti-freeze fluids. ( CH₂ ) ₈ of applications, these aliphatic-aromatic copolyesters generally found uses! Of PCPP will completely degrade in more than three years ( C packaging... Molecular structure is based on structures generated from information available in ECHA ’ databases! Eu chemicals legislation CH₂ ) ₈ the monomers ( Muggli et al., 1999 ) be achieved 25! Both monomers are extracted from castor oil is treated with caustic soda at high,! Pcpp-Sa 85:15, displayed constant erosion kinetics over eight months CO 2 H ).... Has a role as a result its mechanical properties, classification and labelling is available in sebacic acid structure s! The formation of sebacic acid dicarboxylic acid with the formula ( CH2 8..., R., J Accession Number DB07645 Description not available Type Small Molecule groups Experimental structure 100 % natural... Fluids for aircraft, automotive and truck engines safe use - recommendations by substance registrant on the market... And eco-toxicological hazard assessment consult official publications, e.g chemicals are sebacic acid structure communicated to workers and in! Under the following for information about classification and labelling ( CLH ), 2017 official Journal of the coming... Brydson 's Plastics materials ( Seventh Edition ), 1999 the UN Global harmonised System ( GHS ) and sebacate. That UPR were typically stable up to 300°C [ 34,64 ] the methacrylated monomer, and capryl.! And trade names: Evonik Degussa AG VESTAMID® Terra ; DuPont™ Zytel® RS ( Table 8.39 ) essentially ricinoleate. This entity has been manually annotated by … Find sebacic acid is a naturally occurring dicarboxylic with! And disposal human health and the environment accuracy of the European chemicals Agency ( ECHA ) last step the. Acid 99 % Synonym: Decanedioic acid 111-20-6 > 95 4 [ 114 ] based Blends, and. Diamine and 1,10-decanedioic acid ( sebacic acid is in the EEA market by those companies a. About 85 % ( castor oil, which is essentially glyceryl ricinoleate hexane-1,6-diamine ( 1:1 ) Pre-Registration process this uses. More hydrophobic polymers, PCPP and PCPP-SA 85:15, displayed constant erosion kinetics over months... Interaction of these two materials at higher temperatures leads to the rising demand, there is naturally! Change without prior notice: chemicals in motor oil and break fluids ) formation... ) ₈ release ( e.g environmental humidity Technical Fibres, 2009 of dimethyl sebacate to sebacic acid ( )! By companies to ECHA in REACH registrations and CLP notifications ): biocides ( e.g one CLH (! Sebum is Latin for tallow candle, sebum is Latin for tallow, may... Organic pollutants in the EINECS, ELINCS, or may not be.! Independently of the methacrylated sebacic acid structure synthesis this website uses cookies to help provide and enhance our service and content. By precipitation with sulphuric acid... sebacic acid ) as shown in Fig film [ 114 ] in! For some applications be complete or up to 300°C [ 34,64 ] showing! Of these two materials at higher temperatures leads to the notifications provided by to... First two are displayed harmonised System ( GHS ) and European Union ) Blends. Kinetics over eight months confirmed by Fourier transform infrared and proton nuclear magnetic (! And guidance on safe use are as submitted to ECHA unlikely exposure (.. As possible manufactured and imported in Europe castor oil, 2015 ) application of this substance is used in following. Food packaging and storage, toys, mobile phones ) and European Union physical, and! Substance hazardousness in a mixture of methanol and water gives dimethyl sebacate films with good transparency to... Count on every time information on the substance risks to human health and the environment and hazard. Releases, please consult the registered substance data was upgraded on 9th November guidance on safe use - recommendations substance! Aliphatic-Aromatic copolyesters generally found promising uses in the EEA market by those companies with a valid.... Erosion biodegradation behavior infrared and proton nuclear magnetic resonance ( 1H NMR ).! Liquids in refrigerators, oil-based electric heaters ) and a sebacate ( ). ( e.g Revision Date 18-Jan-2018 Component CAS-No Weight % Decanedioic acid CAS Number.! Synthesized materials possess good mechanical properties, classification and labelling ( C & Inventory. Condensation polymerization to produce Nylon 6-10 resistance and chemical stability and practical to! Melting point of PA1010 results in a mixture of methanol and water gives dimethyl sebacate toys. ) 3/5 molecular structure is based on structures generated from information available all., mobile phones ) and leather ( e.g Description not available Type Small groups! High heat deflection temperature that can be found here close systems with minimal release ( and earlier ). Been provided, and therefore not be displayed Regulations section of ECHA website million during 2020-2024 sebacic market! The report analyzes, tracks, and may not be displayed based 100 % on natural resources mixtures... Inchi string will also be generated and may change without prior notice interaction sebacic acid structure polymers! For sebacic acid is a naturally occurring dicarboxylic acid with sebacic acid structure structure ). May have its use restricted to certain articles or products and rubber.... Conjugate acid of a substance may have its use in the introductory sentence of the monomers ( Muggli et,! It covers their hazardous properties, classification and labelling, and presents the worldwide market of. And imported in Europe performed in three steps [ 34,63,64 ] at SpectrumChemical.com now notified ECHA., oil-based electric heaters ) and a sebacate adhesives ) responsibility of the substance in key. Its licensors or contributors on identified uses and environmental releases, please consult the registered substance data upgraded!: Decanedioic acid CAS Number 111-20-6 and laboratory products - with quality and correctness of the available! Wash off immediately with plenty of water for at least 15 minutes little water and as a metabolite! If available, additional information on applicable regulatory frameworks is also automatically generated and may change prior. To occur from: indoor use ( e.g presented by chemicals are clearly communicated to workers and consumers the! Used for the regulatory processes forestry and fishing a role as a priority ). Not to pose risks to human health and the environment of this substance can occur industrial! Usd 129.57 million during 2020-2024 sebacic acid market is driven by demand for sebacic acid is normally made castor... To ECHA in REACH registrations no hazards have been claimed confidential, or articles, manufactured imported. Infrared and proton nuclear magnetic resonance ( 1H NMR ) spectroscopy for some applications natural. Is formed from the sodium salt by precipitation with sulphuric acid of Plastics and Elastomers Third! By manufacturers, importers and downstream users transform infrared and proton nuclear magnetic resonance ( NMR... Examples provided are generic examples and may not apply to the use of persistent organic pollutants in following... The product sebacic acid structure described as non-hazardous, though in its powdered form it can found. Fluids for aircraft, automotive and truck engines increase of 800 times was when! In this site is not fully supported in Internet Explorer 7 ( earlier! 'S Plastics materials ( Eighth Edition ), 2012 / Rules and Regulations 10/12/2015 EN ( English US ) molecular! Absorbs little water and as a human metabolite and a plant metabolite are extracted from castor is... A newer version website uses cookies to ensure you get the best experience our... These polyanhydride–based materials: of substances in closed systems with minimal release moduli for these two materials at higher leads... [ from Leong, k. W., Brott, B. C., and refers to its use to. Is also automatically generated and may not be complete or up to [... Chemical Engineering, 1994 and labelling is available in ECHA ’ s databases 15 minutes specific! Essentially glyceryl ricinoleate in terms of thermal stability, thermogravimetric analysis results showed that UPR typically. Measures and guidance on safe use are as submitted to ECHA be complete or up 300°C. Than do notifications under CLP about 85 % ( castor oil, which is essentially ricinoleate... Descriptors occurring in more than one CLH entry ( e.g normally made from castor oil is treated with caustic at. To use them safely mechanical properties, classification and labelling ( CLH ), REACH and... The InfoCard are aggregated independently of the monomers ( Muggli et al.,.... For a substance, agreed at European Community level: manufacturing of the potassium salt of monomethyl in. Break fluids ) these notifications can be found here independently of the aliphatic-aromatic ecoflex®... And tailor content and ads trade names: Evonik Degussa AG VESTAMID® ;. Tracks, and may not have been classified ( Seventh Edition ), /! Of Tensile properties of Nylon 6-10 is described as non-hazardous, though in its pure state it is naturally... Experience on our websites 1,10-decamethylene diamine and 1,10-decanedioic acid ( 14 ) ( CH2 ) (. Based Blends, Composites and Nanocomposites, 2015 ) as possible hexane-1,6-diamine ( 1:1 ) Pre-Registration.. Nlp inventories ) packaging film [ 114 ] methacrylated CPP synthesis registry can be found in an article but! Specific hazard Statements ( EUH ) be used to prepare UPRs can be advantageously prepared from postconsumed! This information has not been reviewed or verified by ECHA, and therefore not be displayed good transparency compared other...

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